Hydrothermal synthesis and characterization of the lutetium borate-nitrate Lu2B2O5(NO3)2 • 2H2O

被引：14
|
作者：
Ortner, Teresa S. [1 ]
Wurst, Klaus [1 ]
Hejny, Clivia [2 ]
Huppertz, Hubert [1 ]
机构：
[1] Leopold Franzens Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria
[2] Leopold Franzens Univ Innsbruck, Inst Mineral & Petrog, Innrain 52, A-6020 Innsbruck, Austria
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 2016年 / 233卷
关键词：
Lutetium borate-nitrate; Pyroborate; Nitrate; Hydrothermal; Crystal structure; FUNDAMENTAL BUILDING-BLOCKS; BOND-VALENCE PARAMETERS; EARTH BASIC NITRATES; CRYSTAL-STRUCTURES; MAGNESIUM BORATE; HYDROGEN-BONDS; COLEMANITE; MINERALS; GEOMETRY; SPECTRA;
D O I：
10.1016/j.jssc.2015.11.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The lutetium diborate-dinitrate Lu2B2O5(NO3)(2) center dot 2H(2)O was discovered through a hydrothermal synthesis from Lu(NO3)(3) center dot H2O and H3BO3. The compound crystallizes in the space group PT (no. 2) with the lattice parameters a=789.52(5), b=988.62(6), c=1460.33(8) pm, alpha=90.83(1), beta=101.75(1), and gamma=110.02(1) (Z=4). Isolated [B2O5](4-) units show coplanar alignment and the coordinating [NO3](-) groups are stacked perpendicular to the borate plane. Thereby, a novel, open arrangement solely built up from diborate and nitrate groups at a 1:1 ratio is formed. Additionally, Lu2B2O5(NO3)(2) center dot 2H(2)O is characterized by vibrational spectroscopy (IR/Raman). (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码：329 / 334
页数：6
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