A spherical molecular assembly formed by the interplay of hydrophobic and hydrogen bonding interactions. Formation of a hexameric ball

被引：3
|
作者：
Goto, Kenta [1 ]
Miyahara, Yuji [2 ]
Shinmyozu, Teruo [1 ]
机构：
[1] Kyushu Univ, Inst Mat Chem & Engn, Div Appl Mol Chem, Higashi Ku, Fukuoka 8128581, Japan
[2] Kyushu Univ, Grad Sch Sci, Dept Chem, Higashi Ku, Fukuoka 8128581, Japan
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 05期
关键词：
LEUCINE-ZIPPER; CRYSTALLIZATION; 1,3-CYCLOHEXANEDIONE; TRANSFORMATION; POLYMORPHISM; STABILITY; ROSETTES; KINETICS;
D O I：
10.1016/j.tetlet.2009.12.012
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A six-membered ball-like supramolecular structure of 1c was obtained by the interplay of hydrophobic and hydrogen bonding interactions. Preferred H-bonding connectivity and the proximate side-chain groups in a hydrophobic core stabilized to form the ball structure as revealed by making a comparison with the linear tape structure in the crystal polymorph of 1c. (c) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：832 / 835
页数：4
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