Effects of alkyl chain length of monomer and dye-doped type on the electro-optical properties of polymer-dispersed liquid crystal films prepared by nucleophile-initiated thiol-ene click reaction

被引:23
|
作者
Zhang, Li [1 ]
Liu, Yawen [1 ]
Shi, Zhiqing [2 ]
He, Taoyu [1 ]
Gong, Xinjian [3 ]
Geng, Pengfei [3 ]
Gao, Zhenwei [3 ]
Wang, Yinghan [1 ]
机构
[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu, Sichuan, Peoples R China
[2] Shenzhen China Star Optoelect Semicond Display Te, Shenzhen, Guangdong, Peoples R China
[3] Weifang Hengcai Digital Photo Mat Co Ltd, Weifang, Shandong, Peoples R China
关键词
PDLC; alkyl chain length of monomer; reaction temperature; dye type; electro-optical properties; DICHROIC DYE; LIGHT-SCATTERING; PDLC FILMS; CHEMISTRY; BEHAVIOR; MATRIX;
D O I
10.1080/02678292.2019.1673909
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polymer-dispersed liquid crystal (PDLC) films containing a series of monomers with different alkyl chain lengths were prepared by nucleophile-initiated thiol-ene click reaction. The effect of alkyl chain length of monomers, dye and temperature on electro-optical properties of PDLC films was investigated. It was found that the alkyl chain length and polymerisation rate of monomers together determine the size of liquid crystal (LC) droplets, thus affecting the electro-optical properties of PDLC. In addition, the type and content of dyes could be optimised to obtain PDLC materials with better comprehensive properties for display.
引用
收藏
页码:658 / 672
页数:15
相关论文
共 29 条
  • [1] Effects of the chain length of crosslinking agent and dye-doped amount on the electro-optical properties of polymer-dispersed liquid crystal films prepared by nucleophile-initiated thiol-ene click reaction
    Zhang, Li
    Shi, Zhiqing
    He, Taoyu
    Liu, Yawen
    Wang, Yinghan
    LIQUID CRYSTALS, 2020, 47 (01) : 42 - 53
  • [2] Effects of thiol monomers on the electro-optical properties of polymer-dispersed liquid crystal films prepared by nucleophile-initiated thiol-ene click reaction
    Shi, Zhiqing
    Wang, Ying
    Wang, Yinghan
    LIQUID CRYSTALS, 2018, 45 (12) : 1746 - 1752
  • [3] A study on electro-optical properties of polymer dispersed liquid crystal films doped with barium titanate nanoparticles prepared by nucleophile-initiated thiol-ene click reaction
    He, Taoyu
    Yang, Bo
    Zhang, Li
    Shi, Zhiqing
    Gong, Xinjian
    Geng, Pengfei
    Gao, Zhenwei
    Wang, Yinghan
    LIQUID CRYSTALS, 2020, 47 (07) : 1004 - 1018
  • [4] Facile fabrication of polymer-dispersed liquid crystal films via nucleophile-initiated thiol-ene click reaction
    Shi, Zhiqing
    Guan, Yu
    Wang, Fei
    Zhang, Yuliang
    Deng, Feifei
    Liu, Yawei
    Wang, Yinghan
    LIQUID CRYSTALS, 2017, 44 (11) : 1695 - 1700
  • [5] Fabrication of dye-doped polymer-dispersed liquid crystals with low driving voltage based on nucleophile-initiated thiol-ene click reaction
    Shi, Zhiqing
    Shao, Leishan
    Wang, Fei
    Deng, Feifei
    Liu, Yawei
    Wang, Yinghan
    LIQUID CRYSTALS, 2018, 45 (04) : 579 - 585
  • [6] A study on electro-optical properties of polymer dispersed liquid crystal films with thiol-isocyanate-ene ternary network prepared by nucleophile-initiated thiol-ene click reaction and thiol-isocyanate coupling reaction
    He Taoyu
    Yang Bo
    Zhang Li
    Shi Zhiqing
    Gong Xinjian
    Geng Pengfei
    Gao Zhenwei
    Wang Yinghan
    LIQUID CRYSTALS, 2020, 47 (11) : 1624 - 1637
  • [7] Study on electro-optical and adhesion properties of polymer dispersed liquid crystal films from thiol-ene click reaction
    Ren, Yunxiao
    Hu, Wei
    Sun, Chang
    Huang, Junyi
    Hu, Junmei
    Shen, Jiyuan
    He, Wanli
    Zhang, Lanying
    Yuan, Xiaotao
    Yu, Meina
    Yang, Huai
    LIQUID CRYSTALS, 2021, 48 (15) : 2188 - 2199
  • [8] Effects of functionality of thiol monomer on electro-optical properties of polymer-dispersed liquid crystal films
    Sun, Yujian
    Zhang, Cuihong
    Cao, Hui
    Xiao, Jiumei
    Ding, Hangjun
    Li, Fasheng
    Yu, Haifeng
    Yang, Zhou
    Yang, Huai
    LIQUID CRYSTALS, 2017, 44 (07) : 1086 - 1092
  • [9] Effects of monomer alkyl chain length on electro-optical properties of polymer dispersed liquid crystal film
    Zeng Teng
    He Tao-yu
    Wang Ying-han
    CHINESE JOURNAL OF LIQUID CRYSTALS AND DISPLAYS, 2021, 36 (10) : 1362 - 1368
  • [10] Comparative studies of polymer-dispersed liquid crystal films via a thiol-ene click reaction
    Zhong, Tingjun
    Mandle, Richard J.
    Goodby, John W.
    Zhang, Lanying
    Zhang, Cuihong
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2019, 30 (11) : 2781 - 2789