Synthesis of Substituted Styrenes and 3-Vinylphenols Using Ruthenium-Catalyzed Ring-Closing Enyne Metathesis

被引：9
|
作者：
Yoshida, Kazuhiro [1 ]
Nishii, Kana [1 ]
Kano, Yuto [1 ]
Wada, Shiro [1 ]
Yanagisawa, Akira [1 ]
机构：
[1] Chiba Univ, Grad Sch Sci, Dept Chem, Inage Ku, Chiba 2638522, Japan
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 09期
关键词：
OLEFIN METATHESIS; PHENOL DERIVATIVES; CONSTRUCTION; EFFICIENT; CYCLIZATION; DEHYDRATION; OXIDATION; BENZENE;
D O I：
10.1021/jo500561z
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The synthesis of substituted styrenes 3 and 3-vinylphenols 9 was achieved by ring-closing enyne metathesis (RCEM)/dehydration of 7 and RCEM/tautomerization of 8, respectively. Those methods provide selective access to unique aromatic compounds and solve the problem of regioisomer formation.
引用
收藏
页码：4231 / 4239
页数：9
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