Kinetic modelling of regioselectivity in alkenes hydroformylation over rhodium

被引：13

作者：

Murzin, Dmitry Yu. ^{[1
]}

Bernas, Andreas ^{[1
]}

Salmi, Tapio ^{[1
]}

机构：

[1] Abo Akad Univ, SF-20500 Turku, Finland

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2010年 / 315卷 / 02期

关键词：

Hydroformylation; Alkene; Rhodium; Regioselectivity; Modelling; PROPENE; INDUSTRIAL; CATALYSTS;

D O I：

10.1016/j.molcata.2009.06.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Propene hydroformylation was performed with rhodium triphenylphosphine catalyst with hydrogen and CO partial pressure varied in the range of 8-15 bar The regioselectivity was independent on the concentration of reactants, displaying dependence only oil the ligand concentration A kinetic model was proposed based oil the mechanism of alkene hydroformylation and compared with experimental observations. Numerical data fitting was performed showing good correspondence of reaction rates and regioselectivity with experimental data (C) 2009 Elsevier B.V. All rights reserved

引用

页码：148 / 154

页数：7

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