Aldol condensation of acetone over Mg-Al mixed oxides catalyst prepared by a citric acid route

被引:11
|
作者
Ma, Chunxiang [1 ]
Liu, Gang [1 ]
Wang, Zhenlu [1 ]
Li, Yufei [1 ]
Zheng, Jing [1 ]
Zhang, Wenxiang [1 ]
Jia, Mingjun [1 ]
机构
[1] Jilin Univ, Coll Chem, Key Lab Surface & Interface Chem Jilin Prov, Changchun 130012, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
Aldol condensation; Isophorone; Citric acid; Mg-Al mixed oxide; OLIGOMERIZATION; HYDROTALCITES; METHYLATION; SELECTIVITY;
D O I
10.1007/s11144-009-0055-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mg-Al mixed oxides with different Mg/Al molar ratios were prepared by using a citric acid route and tested as catalysts for the gas phase self-aldol condensation of acetone to isophorone. The sample with Mg/Al ratio of 1.0 exhibits relatively high activity and stability, and its catalytic performance could be further improved by adding alkali promoter.
引用
收藏
页码:149 / 156
页数:8
相关论文
共 50 条
  • [1] Aldol condensation of acetone over Mg–Al mixed oxides catalyst prepared by a citric acid route
    Chunxiang Ma
    Gang Liu
    Zhenlu Wang
    Yufei Li
    Jing Zheng
    Wenxiang Zhang
    Mingjun Jia
    Reaction Kinetics and Catalysis Letters, 2009, 98 : 149 - 156
  • [2] Aldol condensation of furfural and acetone over Mg-Al layered double hydroxides and mixed oxides
    Hora, Lukas
    Kelbichova, Vendula
    Kikhtyanin, Oleg
    Bortnovskiy, Oleg
    Kubicka, David
    CATALYSIS TODAY, 2014, 223 : 138 - 147
  • [3] Gas-phase Aldol Condensation of Acetone over Mg-Al Oxides Prepared by Co-precipitation Methods
    Ma Chun-Xiang
    Liu Gang
    Zhu Wan-Chun
    Wang Li-Xia
    Li Yu-Fei
    Zhang Wen-Xiang
    Jia Ming-Jun
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2009, 30 (12): : 2429 - 2433
  • [4] Effect of the acid-base properties of Mg-Al mixed oxides on the catalyst deactivation during aldol condensation reactions
    Díez, VK
    Apesteguía, CR
    Di Cosimo, JI
    LATIN AMERICAN APPLIED RESEARCH, 2003, 33 (02) : 79 - 86
  • [5] Aldol condensation of benzaldehyde and heptanal: a comparative study of laboratory and industrially prepared Mg-Al mixed oxides
    Vrbkova, Eva
    Tisler, Zdenek
    Vyskocilova, Eliska
    Kadlec, David
    Cerveny, Libor
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2018, 93 (01) : 166 - 173
  • [6] Catalytic condensation of aromatic aldehydes with acetone on activated Mg-Al mixed oxides
    Campanati, M
    Franceschini, S
    Piccolo, O
    Vaccari, A
    Zicmanis, A
    CATALYSIS COMMUNICATIONS, 2004, 5 (03) : 145 - 150
  • [7] Acetone gas phase condensation on Mg-Al composite oxides catalysts prepared via Mg-Al hydrotalcites precursor
    Wang Fang-Zhu
    Yang Kun
    Chai Yong-Ming
    Gao Peng-Cheng
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (09) : 1417 - 1423
  • [8] Aldol Condensation of Furfural with Acetone Over Mg/Al Mixed Oxides. Influence of Water and Synthesis Method
    Parejas, Almudena
    Cosano, Daniel
    Hidalgo-Carrillo, Jesus
    Rafael Ruiz, Jose
    Marinas, Alberto
    Jimenez-Sanchidrian, Cesar
    Urbano, Francisco J.
    CATALYSTS, 2019, 9 (02):
  • [9] Influence of thermal treatment conditions on the activity of hydrotalcite-derived Mg-Al oxides in the aldol condensation of acetone
    Kustrowski, P
    Sulkowska, D
    Chmielarz, L
    Rafalska-Lasocha, A
    Dudek, B
    Dziembaj, R
    MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 78 (01) : 11 - 22
  • [10] Aldol Condensation of Benzaldehyde and Heptanal Over Zinc Modified Mixed Mg/Al Oxides
    Tisler, Zdenek
    Vrbkova, Eva
    Kocik, Jaroslav
    Kadlec, David
    Vyskocilova, Eliska
    Cerveny, Libor
    CATALYSIS LETTERS, 2018, 148 (07) : 2042 - 2057