SiOx/C composite from rice husks as an anode material for lithium-ion batteries

被引:78
|
作者
Ju, Yanming [1 ]
Tang, Joel A. [2 ]
Zhu, Kai [1 ]
Meng, Yuan [1 ]
Wang, Chunzhong [1 ,3 ]
Chen, Gang [1 ,3 ]
Wei, Yingjin [1 ]
Gao, Yu [1 ]
机构
[1] Jilin Univ, Coll Phys, Key Lab Phys & Technol Adv Batteries, Minist Educ, Changchun 130012, Peoples R China
[2] Johns Hopkins Univ, Dept Chem, Charles & 34Th St, Baltimore, MD 21218 USA
[3] Jilin Univ, State Key Lab Superhard Mat, Changchun 130012, Peoples R China
基金
中国国家自然科学基金;
关键词
Rice Husks; Argon/hydrogen atmosphere; SiOx/C; Lithium-ion batteries; HIGH-PERFORMANCE ANODE; POROUS CARBON; SILICON; NANOPARTICLES; ELECTRODE; STRAW;
D O I
10.1016/j.electacta.2016.01.095
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
SiOx/C composite material derived directly from agricultural rice husk byproducts through an economically viable and environmentally benign approach has been explored to be used as an anode for rechargeable lithium batteries. Rice husks were converted into a SiOx/C composite directly by heat treatment under argon/hydrogen atmosphere, at a temperature of 900 degrees C. The composite contains SiOx surrounded by an amorphous carbon matrix. A steady state reversible capacity of nearly 600 mAh g (1) was delivered at 100 mA g (1) current density after 100 cycles. The improved performance of the SiOx/C composite anode over other agricultural byproduct derived carbon materials is believed to be due to the presence of low valence silicon. The filth-to-wealth conversion of rice husks to battery material is a highly energy efficient process with great economic and environmental benefits. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:411 / 416
页数:6
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