A new phenomenological model describing conduction in electrolyte solutions

被引：0
|
作者：
Semenescu, G [1 ]
Cioaca, C
Iorga, B
机构：
[1] Univ Pitesti, Fac Sci, Pitesti, Romania
[2] Univ Bucharest, Fac Chem, Dept Phys, Bucharest 70346, Romania
来源：
ACTA CHIMICA SLOVENICA | 2000年 / 47卷 / 02期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mechanism for electronic conduction in electrolyte solutions is presented. The structure of the electrode-electrolyte interface and the molecules in the ion solvation layer are the important element in this mechanism. The electrolyte chooses between one structure with a minimum electrical resistance and another one with a high electrical resistance as a function of the scanning rate value of the potential. The minimum resistance in the electronic conduction of electrolyte solutions is achieved basing on the multiwire-insulated conductor.
引用
收藏
页码：133 / 141
页数：9
相关论文
共 50 条
  • [1] CONDUCTION MODEL OF CONCENTRATED ELECTROLYTE-SOLUTIONS
    KHALDNA, YL
    SOVIET ELECTROCHEMISTRY, 1976, 12 (11): : 1598 - 1599
  • [2] A Model Describing the Osmotic Coefficients and the Activities of Water for Electrolyte Solutions
    Fang, Zheng
    ASIAN JOURNAL OF CHEMISTRY, 2011, 23 (12) : 5384 - 5392
  • [3] DETERMINATION OF THE PHENOMENOLOGICAL COEFFICIENTS DESCRIBING THE TRANSFER OF ELECTROLYTE THROUGH SOIL
    PETROVA, ZM
    OSTAPENKO, IS
    SOVIET SOIL SCIENCE, 1991, 23 (07): : 93 - 100
  • [4] A new model for the viscosity of electrolyte solutions
    Jiang, JW
    Sandler, SI
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (25) : 6267 - 6272
  • [5] MODEL FOR DESCRIBING ACTIVITY-COEFFICIENTS IN MIXED ELECTROLYTE AQUEOUS-SOLUTIONS
    LU, XH
    MAURER, G
    AICHE JOURNAL, 1993, 39 (09) : 1527 - 1538
  • [6] Modified Microheterogeneous Model for Describing Electrical Conductivity of Membranes in Dilute Electrolyte Solutions
    Nichka, V. S.
    Mareev, S. A.
    Porozhnyy, M., V
    Shkirskaya, S. A.
    Safronova, E. Yu
    Pismenskaya, N. D.
    Nikonenko, V. V.
    MEMBRANES AND MEMBRANE TECHNOLOGIES, 2019, 1 (03) : 190 - 199
  • [7] Modified Microheterogeneous Model for Describing Electrical Conductivity of Membranes in Dilute Electrolyte Solutions
    V. S. Nichka
    S. A. Mareev
    M. V. Porozhnyy
    S. A. Shkirskaya
    E. Yu. Safronova
    N. D. Pismenskaya
    V. V. Nikonenko
    Membranes and Membrane Technologies, 2019, 1 : 190 - 199
  • [8] ELECTROPHORETIC EFFECT FOR CONDUCTION IN ELECTROLYTE SOLUTIONS
    CARMAN, PC
    JOURNAL OF THE SOUTH AFRICAN CHEMICAL INSTITUTE, 1975, 28 (02): : 264 - 271
  • [9] New modified Wilson model for electrolyte solutions
    Xu, X
    Macedo, EA
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (22) : 5702 - 5707
  • [10] New local composition model for electrolyte solutions
    Sadeghi, R
    FLUID PHASE EQUILIBRIA, 2005, 231 (01) : 53 - 60
12345