Development trends of direct methanol fuel cells

被引:3
|
作者
Kamo, T [1 ]
机构
[1] Hitachi Ltd, Hitachi Res Lab, Hitachi, Ibaraki 3191292, Japan
关键词
DMFC; methanol; MEA; polymer electrolyte; crossover; catalyst;
D O I
10.5796/electrochemistry.70.915
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
DMFC is one of the fuel cells that generate electricity using aqueous methanol solution as a fuel and oxygen or air as an oxidizing agent. By operation of DMFC, methanol is oxidized by oxygen to produce carbon dioxide and water. A single cell of DMFC is composed of an MEA that is held between separators. MEA is manufactured by laminating anode and cathode on both sides of polymer electrolyte membrane which is made of sulfonized perfluorocarbon polymer or hydrocarbon polymer. Recently limiting current has increased up to 600 mA/cm(2) owing to the advance in MEA technology. DMFC can be downsized because they use liquid fuel directly, which is more preferable for applications such as portable and mobile use. However, there are many technological problems that should be overcome to realize DMFC system to be used for those applications. Especially, a breakthrough in materials research should be necessary in order to decrease methanol crossover and to improve catalytic activity.
引用
收藏
页码:915 / 919
页数:5
相关论文
共 50 条
  • [1] Fuel cells - Methanol behavior in direct methanol fuel cells
    Paik, Younkee
    Kim, Seong-Soo
    Han, Oc Hee
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (01) : 94 - 96
  • [2] Development of electro catalysts for direct methanol fuel cells
    Du Juan
    Yuan Xianxia
    Chao Yajun
    Ma Zifeng
    RARE METAL MATERIALS AND ENGINEERING, 2007, 36 (07) : 1309 - 1312
  • [3] Direct methanol fuel cells
    Dubois, JC
    ACTUALITE CHIMIQUE, 2001, (12): : 58 - 62
  • [4] Direct methanol fuel cells
    McGrath, KM
    Prakash, GKS
    Olah, GA
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2004, 10 (07) : 1063 - 1080
  • [5] Development of composite anode electrocatalyst for direct methanol fuel cells
    Li, Xiaoxia
    Qiu, Xinping
    Zhao, Long
    Chen, Liquan
    Zhu, Wentao
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 2009, 39 (10) : 1779 - 1787
  • [6] Development of Membrane Electrode Assembly for Direct Methanol Fuel Cells
    Suo Chunguang
    Liu Xiaowei
    Zhang Yufeng
    Zhang Bo
    Zhang Peng
    Wang Luwen
    PROGRESS IN CHEMISTRY, 2009, 21 (7-8) : 1662 - 1671
  • [7] Development of porous carbon electrodes for direct methanol fuel cells
    Ramkumar, R.
    Dheenadayalan, S.
    Pattabiraman, R.
    Journal of Power Sources, 69 (1-2): : 75 - 80
  • [8] Recent Development of Anode Electrocatalysts for Direct Methanol Fuel Cells
    Luo Yuanlai
    Liang Zhenxing
    Liao Shijun
    CHINESE JOURNAL OF CATALYSIS, 2010, 31 (02) : 141 - 149
  • [9] Development of composite anode electrocatalyst for direct methanol fuel cells
    Xiaoxia Li
    Xinping Qiu
    Long Zhao
    Liquan Chen
    Wentao Zhu
    Journal of Applied Electrochemistry, 2009, 39 : 1779 - 1787
  • [10] Development of porous carbon electrodes for direct methanol fuel cells
    Ramkumar, R
    Dheenadayalan, S
    Pattabiraman, R
    JOURNAL OF POWER SOURCES, 1997, 69 (1-2) : 75 - 80