Oxidation of Cysteinate Anions Immobilized in the Interlamellar Space of CaAl-Layered Double Hydroxide

被引：0

作者：

Timar, Zita ^{[1
,2
,3
]}

Hung, Truong Ngoc ^{[1
,2
,3
]}

Pravda, Cora ^{[4
]}

Konya, Zoltan ^{[4
,5
]}

Kukovecz, Akos ^{[4
]}

Sipos, Pal ^{[1
,2
,6
]}

Varga, Gabor ^{[1
,2
,7
]}

Palinko, Istvan ^{[1
,2
,3
]}

机构：

[1] Univ Szeged, Mat & Solut Struct Res Grp, Aradi Vertanuk Tere 1, H-6720 Szeged, Hungary

[2] Univ Szeged, Interdisciplinary Excellence Ctr, Inst Chem, Aradi Vertanuk Tere 1, H-6720 Szeged, Hungary

[3] Univ Szeged, Dept Organ Chem, Dom Ter 8, H-6720 Szeged, Hungary

[4] Univ Szeged, Dept Appl & Environm Chem, H-6720 Szeged, Hungary

[5] MTA SZTE React Kinet & Surface Chem Res Grp, H-6720 Szeged, Hungary

[6] Univ Szeged, Dept Inorgan & Analyt Chem, Dom Ter 7, H-6720 Szeged, Hungary

[7] Univ Szeged, Dept Phys Chem & Mat Sci, H-6720 Szeged, Hungary

来源：

MATERIALS | 2021年 / 14卷 / 05期

关键词：

cysteine oxo acids; cysteinate oxidation to cystinate; cysteinate anion-pillared CaAl-layered double hydroxide (LDH); confined space— molecular reactor; NITRILE HYDRATASE; ACID; CYSTINE; SPECTROSCOPY; MEDIA;

D O I：

10.3390/ma14051202

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

L-Cysteinate-intercalated CaAl-layered double hydroxide (LDH) was prepared by the co-precipitation method producing highly crystalline hydrocalumite phase with a well-pillared interlayer gallery. The obtained materials were characterized by X-ray diffractometry, IR as well as Raman spectroscopies. By performing interlamellar oxidation reactions with peracetic acid as oxidant, oxidation of cysteinate to cystinate in aqueous and cysteinate sulfenic acid in acetonic suspensions occurred. The oxidations could be performed under mild conditions, at room temperature, under neutral pH and in air. It has been shown that the transformation pathways are due to the presence of the layered structure, that is, the confined space of the LDH behaved as molecular reactor.

引用

页码：1 / 10

页数：10

共 50 条

[1] Optimisation of the synthesis parameters of mechanochemically prepared CaAl-layered double hydroxide
Ferencz, Zsolt
Kukovecz, Akos
Konya, Zoltan
Sipos, Pal
Palinko, Istvan
[J]. APPLIED CLAY SCIENCE, 2015, 112 : 94 - 99
[2] Polymer Coated CaAl-Layered Double Hydroxide Nanomaterials for Potential Calcium Supplement
Kim, Tae-Hyun
Lee, Jeong-A
Choi, Soo-Jin
Oh, Jae-Min
[J]. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2014, 15 (12): : 22563 - 22579
[3] CaAl-layered double hydroxide as a drug delivery system: effects on solubility and toxicity of the antiretroviral efavirenz
Danilo Augusto Ferreira Fontes
Magaly Andreza Marques de Lyra
Jeyce Kelle Ferreira de Andrade
Giovanna Christinne Rocha de Medeiros Schver
Larissa Araújo Rolim
Teresinha Gonçalves da Silva
José Lamartine Soares-Sobrinho
Severino Alves-Júnior
Pedro José Rolim-Neto
[J]. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2016, 85 : 281 - 288
[4] Esterification reactions with acetate- or benzoate-containing CaAl-layered double hydroxide samples
Timar, Zita
Sztankovics, Dusan
Varga, Gabor
Sipos, Pal
Palinko, Istvan
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2019, 1186 : 303 - 306
[5] CaAl-layered double hydroxide as a drug delivery system: effects on solubility and toxicity of the antiretroviral efavirenz
Ferreira Fontes, Danilo Augusto
Marques de Lyra, Magaly Andreza
Ferreira de Andrade, Jeyce Kelle
Rocha de Medeiros Schver, Giovanna Christinne
Rolim, Larissa Araujo
da Silva, Teresinha Goncalves
Soares-Sobrinho, Jose Lamartine
Alves-Junior, Severino
Rolim-Neto, Pedro Jose
[J]. JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2016, 85 (3-4) : 281 - 288
[6] One-pot synthesis of CaAl-layered double hydroxide–methotrexate nanohybrid for anticancer application
Manjusha Chakraborty
Manoj K Mitra
Jui Chakraborty
[J]. Bulletin of Materials Science, 2017, 40 : 1203 - 1211
[7] Ultrasonically-enhanced mechanochemical synthesis of CaAl-layered double hydroxides intercalated by a variety of inorganic anions
Szabados, Marton
Meszaros, Rebeka
Erdei, Szabolcs
Konya, Zoltan
Kukovecz, Akos
Sipos, Pal
Palinko, Istvan
[J]. ULTRASONICS SONOCHEMISTRY, 2016, 31 : 409 - 416
[8] A General and Scalable Formulation of Pure CaAl-Layered Double Hydroxide via an Organic/Water Solution Route
Xu, Sailong
Zhang, Bowen
Chen, Zhanrui
Yu, Jianhui
Evans, David G.
Zhang, Fazhi
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (11) : 6567 - 6572
[9] One-pot synthesis of CaAl-layered double hydroxide-methotrexate nanohybrid for anticancer application
Chakraborty, Manjusha
Mitra, Manoj K.
Chakraborty, Jui
[J]. BULLETIN OF MATERIALS SCIENCE, 2017, 40 (06) : 1203 - 1211
[10] Synthesis and properties of CaAl-layered double hydroxides of hydrocalumite-type
Toth, Viktor
Sipiczki, Monika
Pallagi, Attila
Kukovecz, Akos
Konya, Zoltan
Sipos, Pal
Palinko, Istvan
[J]. CHEMICAL PAPERS, 2014, 68 (05) : 633 - 637

← 1 2 3 4 5 →