B, N-codoped graphene nanoribbons supported Pd nanoparticles for ethanol electrooxidation enhancement

被引:62
|
作者
Liu, Qi [1 ]
Fan, Jinchen [1 ]
Min, Yulin [1 ]
Wu, Tong [1 ]
Lin, Yan [1 ]
Xu, Qunjie [1 ]
机构
[1] Shanghai Univ Elect Power, Coll Environm & Chem Engn, Shanghai Key Lab Mat Protect & Adv Mat Elect Powe, Shanghai 200090, Peoples R China
基金
美国国家科学基金会;
关键词
FORMIC-ACID OXIDATION; DOPED GRAPHENE; CARBON NANOTUBES; ALKALINE MEDIA; METHANOL OXIDATION; FUEL-CELL; ELECTROCATALYSTS; PALLADIUM; CATALYSTS; PERFORMANCE;
D O I
10.1039/c6ta01136e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, B, N-codoped graphene nanoribbons (BN-GNRs) were prepared on a large scale via a one-pot hydrothermal method with GNRs and an ammonium fluoroborate (NH4BF4) mixture and served as the support for Pd loading targeted for efficient ethanol electrooxidation. The synthesized Pd/BN-GNRs catalysts were characterized by TEM, XRD, XPS and electrochemical methods. The results showed that the Pd nanoparticles were uniformly loaded on BN-GNRs and the Pd/BN-GNRs exhibited much enhanced electrocatalytic activity and stability compared with Pd/GNRs and Pd/C.
引用
收藏
页码:4929 / 4933
页数:5
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