Reactivity of furylhydroperoxides in asymmetric oxidation and kinetic resolution

被引:27
|
作者
Lattanzi, A [1 ]
Bonadies, F [1 ]
Scettri, A [1 ]
机构
[1] UNIV ROMA LA SAPIENZA,CTR CNR CHIM SOSTANZE ORGAN NAT,DIPARTIMENTO CHIM,I-00185 ROME,ITALY
关键词
D O I
10.1016/S0957-4166(97)00202-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Furylhydroperoxides can be successfully employed in the enantioselective oxidation of allylic alcohols and sulfides under Sharpless-type conditions. Their kinetic resolution provides a mean both to chiral furylhydroperoxides and furylalcohols. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:2141 / 2151
页数:11
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