Compatibility, mechanical properties and stability of blends of polylactide and polyurethane based on poly(ethylene glycol)-b-polylactide copolymers by chain extension with diisocyanate

A series of novel biodegradable polyurethanes (PELU) based on poly(ethylene glycol)-b-polylactide co-polymers were prepared by chain extension with isophorone diisocyanate (IPDI). The PELUs were used to toughen polylactide (PLA) by melt blending. The results of DSC and SEM uniformly indicated that the PELUs were partially compatible with PIA and the PLA segments in PELU could effectively improve the compatibility between PLA and PELU. PELU as a plasticizer could significantly improve the toughness of PLA materials and remain their high strength and modulus. When the PELU content was 10-20 wt%, the elongation at break of PLA/PELU-40/ADR (0.4 wt%) and PLA/PELU-50/ADR (0.4 wt%) reached up to 250% -350%. When the PELU content was 20 wt, the tensile strength and modulus of PIA blends containing PELU-30, PELU-40 and PELU-50 maintained 35-38 MPa and 1300-1500 MPa, respectively. The moisture absorption of the PLA materials enhanced because of blending with PELU containing PEG segments, but the hydrolytic degradation property of PIA materials was little affected by this. (C) 2016 Elsevier Ltd. All rights reserved.