Crystal structure of a μ-oxo-bridged dimeric iron(III) complex

被引：3

作者：

Yahsi, Y. ^{[1
]}

Gungor, E. ^{[1
]}

Kazak, C. ^{[2
]}

Kara, H. ^{[1
,3
]}

机构：

[1] Balikesir Univ, Fac Art & Sci, Dept Phys, Balikesir, Turkey

[2] Ondokuz Mayis Univ, Fac Art & Sci, Dept Phys, Samsun, Turkey

[3] Mugla Sikti Kocman Univ, Dept Phys, Fac Sci, Mugla, Turkey

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2015年 / 56卷 / 08期

关键词：

synthesis; Schiff-base ligands; iron(III) complexes; X-ray crystal structure analysis; oxo bridged structure; NONHEME IRON ENZYMES; X-RAY STRUCTURES; MAGNETIC-PROPERTIES; ALKANE FUNCTIONALIZATION; BIOMIMETIC OXIDATION; DIIRON(III) COMPLEX; MOLECULAR-STRUCTURE; SPIN-CROSSOVER; SCHIFF-BASES; ACTIVE-SITE;

D O I：

10.1134/S0022476615080120

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A dimeric [{Fe(5-ClL1)}(2)(mu-O)], [H-2-5-ClL1 = N,N'-bis(5-chloro-2-hydroxybenzylidene)-2-methylpropane-1,2-diamine] tetradentate Schiff-base complex, 1, has been synthesized and its crystal structure has been determined by single crystal X-ray diffraction analysis. Structural analysis of complex 1 shows that the complex is a centrosymmetric dimer. Each of the Fe(III) ions has a five-coordinate geometry and one oxygen atom bridges two Fe(III) ions to form a mu-oxo structure. The geometry around iron atom can be described as a square based pyramid with the FeN2O2 coordination plane and oxo ligand.

引用

页码：1540 / 1544

页数：5

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