Tuneable side-chain supramolecular polymer

被引：21
|
作者：
Cooke, Graeme
Garety, James F.
Hewage, Shanika Gunatilaka
Jordan, Brian J.
Rabani, Gouher
Rotello, Vincent M.
Woisel, Patrice
机构：
[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland
[2] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA
[3] Univ Sci & Technol, Lab Chim Organ & Macromol, F-59655 Villeneuve Dascq, France
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 03期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1021/ol062846z
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A random copolymer containing 1,5-dialkyloxynaphthalene moieties has been synthesized using atom-transfer radical polymerization. We have shown that this polymer has the ability to form complexes with the tetracationic cyclophane cyclobis(paraquat-p-phenylene) (CBPQT(4+)) and that electrochemical reduction of the cyclophane or the addition of a competing guest for the cavity of the cyclophane results in disassembly of the supramolecular polymer.
引用
收藏
页码：481 / 484
页数：4
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