Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond

被引：3
|
作者：
Yamaguchi, Tadashi [1 ]
Yoshiya, Kohei [1 ]
机构：
[1] Waseda Univ, Sch Adv Sci & Engn, Dept Chem & Biochem, Tokyo 1698555, Japan
来源：
INORGANIC CHEMISTRY | 2019年 / 58卷 / 15期
关键词：
X-RAY CRYSTAL; BOOLEAN-AND-P; OXIDATIVE-ADDITION-REACTIONS; MOLECULAR-STRUCTURE; MERCURY(II) CARBOXYLATES; AXIAL LIGAND; PLATINUM(III) COMPLEXES; BINUCLEAR COMPLEXES; COVALENT BRIDGES; BUILDING-BLOCKS;
D O I：
10.1021/acs.inorgchem.9b00978
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) angstrom, and the other is the Pt -> Hg -> Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) angstrom, and one metal-metal dative bond, Pt -> Hg = 2.6635(7) angstrom.
引用
收藏
页码：9548 / 9552
页数：5
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