Crystal structure of the molecular addition compound diphenylchloroborane•tetrahydrofuran

被引：12
|
作者：
Cross, WI [1 ]
Lightfoot, MP [1 ]
Mair, FS [1 ]
Pritchard, RG [1 ]
机构：
[1] Univ Manchester, Dept Chem, Manchester M60 1QD, Lancs, England
来源：
INORGANIC CHEMISTRY | 2000年 / 39卷 / 12期
关键词：
D O I：
10.1021/ic991148q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystalline Ph2BCl·O(CH2)4 is an unexpectedly stable complex containing an intact THF ligand in the presence of a boron halide bond. The short B-O and long B-Cl bonds of this ether cleavage precursor complex are rationalized using Gillespie's ligand close-packing arguments.
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页码：2690 / +
页数：4
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