A novel one-dimensional coordination polymer with Cd2+ and diethylenetriaminepentaacetic acid

被引：20
|
作者：
Paz, FAA [1 ]
Bond, AD [1 ]
Khimyak, YZ [1 ]
Klinowski, J [1 ]
机构：
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷
关键词：
D O I：
10.1107/S0108270102019960
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
catena-Poly[[[bis[diaqua(4,4'-bipyridine)cadmium(II)]-bis[mu-(N"-carboxymethyldiethylenetriamine-N,N,N',N"-tetraacetato)cadmium(II)]]-mu-4,4'-bipyridine] tetradecahydrate], [Cd-4 (C14H19N3O10)(2) (C10H8N2)(3) (H2O)(4)] . 14H(2)O or [Cd-4 (HDTPA)(2) (BPY)(3) (H2O)(4)] . 14H(2)O, where BPY is 4,4'-bipyridine and HDTPA(4-) is N"-carboxymethyldiethylenetriamine-N,N,N',N"-tetraacetate, consists of a one-dimensional coordination polymer formed from a secondary building unit which comprises four Cd centres. The chain structure of the title compound was obtained by the use of a multidentate organic ligand, N,N,N',N",N"-diethylenetriaminepentaacetic acid (H(5)DTPA), which forms multiple chelate rings with the Cd metal centres. An extended network is formed via hydrogen bonds.
引用
收藏
页码：M608 / M610
页数：3
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