Kinetic study on the oxidation of trichlorophenol using hydrogen peroxide and an iron(III) complex of tetrasulfonatophthalocyanine catalyst

被引:15
|
作者
Kasuga, K [1 ]
Mori, K [1 ]
Sugimori, T [1 ]
Handa, M [1 ]
机构
[1] Shimane Univ, Fac Sci & Engn, Dept Mat Sci, Matsue, Shimane 6908504, Japan
关键词
D O I
10.1246/bcsj.73.939
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An oxidative decomposition of TCP, catalyzed by the title complex in the presence of hydrogen peroxide, was studied kinetically. The decrease in the initial reaction rate ill an acidic solution resulted from a depression of the proton dissociation of hydrogen peroxide.
引用
收藏
页码:939 / 940
页数:2
相关论文
共 50 条
  • [1] Unusual kinetic role of a water-soluble iron(III) porphyrin catalyst in the oxidation of 2,4,6-trichlorophenol by hydrogen peroxide
    Lente, G
    Espenson, JH
    [J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2004, 36 (08) : 449 - 455
  • [2] Catalytical kinetic determination of hydrogen peroxide using iron-tetrasulfonatophthalocyanine (with γ-CD) as a mimetic enzyme of peroxidase
    Yuan, H
    Cai, RX
    Pan, ZT
    [J]. ANALYTICAL LETTERS, 2003, 36 (02) : 277 - 286
  • [3] Kinetics of starch oxidation using hydrogen peroxide as an environmentally friendly oxidant and an iron complex as a catalyst
    Tolvanen, P.
    Maki-Arvela, P.
    Sorokin, A. B.
    Salmi, T.
    Murzin, D. Yu.
    [J]. CHEMICAL ENGINEERING JOURNAL, 2009, 154 (1-3) : 52 - 59
  • [4] KINETIC-STUDY OF HYDROGEN-PEROXIDE REACTION WITH HYDROXONITRILOTRI(METHYLENEPHOSPHONATO)IRON(III) COMPLEX
    RIZKALLA, EN
    ELKHALEK, MA
    ANIS, SS
    [J]. TRANSITION METAL CHEMISTRY, 1989, 14 (02) : 131 - 134
  • [5] Mathematical modeling of starch oxidation by hydrogen peroxide in the presence of an iron catalyst complex
    Salmi, Tapio
    Tolvanen, Pasi
    Warna, Johan
    Maki-Arvela, Paivi
    Murzin, Dmitry
    Sorokin, Alexander
    [J]. CHEMICAL ENGINEERING SCIENCE, 2016, 146 : 19 - 25
  • [6] Kinetic study of oxidation of cyclohexane using complex catalyst
    Jhansi, M.
    Kishore, L.
    Kumar, Anil
    [J]. AICHE JOURNAL, 2007, 53 (06) : 1550 - 1561
  • [7] Selective Oxidation of Alcohols to Aldehydes by Hydrogen Peroxide Using Hexamolybdochromate(III) as Catalyst
    Mardur, S. P.
    Gokavi, G. S.
    [J]. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2010, 7 (02) : 441 - 446
  • [8] Selective oxidation of alcohols to aldehydes by hydrogen peroxide using hexamolybdochromate(III) as catalyst
    S. P. Mardur
    G. S. Gokavi
    [J]. Journal of the Iranian Chemical Society, 2010, 7 : 441 - 446
  • [9] KINETIC STUDY OF HYDROGEN-PEROXIDE OXIDATION OF CR(III) TO CR(VI)
    MORROW, JI
    KNOBLOWITZ, M
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, (169): : 176 - 176
  • [10] Kinetic study of oxidation of cyclohexanol using bimetallic iron-copper macrocyclic complex catalyst
    Jhansi, M.
    Kishore, L.
    Anand, K. A.
    Kumar, Anil
    [J]. CATALYSIS COMMUNICATIONS, 2008, 10 (03) : 285 - 290