Recent Progress in Liquid Electrolyte-Based Li-S Batteries: Shuttle Problem and Solutions

被引：61
|
作者：
Gu, Sui [1 ]
Sun, Changzhi [1 ]
Xu, Dong [1 ]
Lu, Yang [1 ]
Jin, Jun [1 ]
Wen, Zhaoyin [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Mat Energy Convers, Shanghai 200050, Peoples R China
来源：
ELECTROCHEMICAL ENERGY REVIEWS | 2018年 / 1卷 / 04期
基金：
国家重点研发计划; 中国国家自然科学基金;
关键词：
Li-S battery; Shuttle effect; Electrolyte additive; Solid-state electrolyte; LITHIUM-SULFUR BATTERIES; AMORPHOUS CONCENTRATED LIQUID; TEMPERATURE IONIC LIQUIDS; CATION SOLVATE STRUCTURES; ETHER-BASED ELECTROLYTES; GEL POLYMER ELECTROLYTE; HIGH-ENERGY DENSITY; HIGH-PERFORMANCE; ELECTROCHEMICAL PROPERTIES; SOLID-ELECTROLYTE;
D O I：
10.1007/s41918-018-0021-0
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Lithium sulfur batteries (LSBs) are among the most promising candidates for next-generation high-energy lithium batteries. However, the polysulfide shuttle effect remains a key obstacle in the practical application of LSBs. Liquid electrolytes, which transport lithium ions between electrodes, play a vital role in battery performances due to the dissolution of polysulfides, and recently, researchers have shown that LSB performances can be greatly improved through the confinement of polysulfides within cathodes. Inspired by this, growing efforts are been devoted to the suppression of the shuttle effect in LSBs by using liquid electrolytes, such as controlling the solubility of solvents and intercepting shuttle reactions. In this review, the design of applicable electrolytes and their functionality on the shuttle effect will be outlined and discussed. In addition, perspectives regarding the future research of LSBs will be presented.Graphical Abstract
引用
收藏
页码：599 / 624
页数：26
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