Analysis of (1,2) (1,3) and (2,3) bands in the c3Πu-b3Πg system of P2

被引:0
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作者
Wu Ling
Zheng Li-Juan
Kaniki Kakule
Chen Yang-Qin
Yang Xiao-Hua [1 ]
机构
[1] E China Normal Univ, Key Lab Opt & Magnet Resonance Spect, Shanghai 200062, Peoples R China
[2] E China Normal Univ, Dept Phys, Shanghai 200062, Peoples R China
[3] Hangzhou Dianzi Univ, Inst Mat Phys, Hangzhou 310018, Peoples R China
[4] Univ Kinshasa, Fac Engn, Kinshasa 11, DEM REP CONGO
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中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We investigate the high resolution absorption spectroscopy of P-2 radical, generated in ac glow discharge of PCl3 buffered with helium, using optical heterodyne magnetic rotation enhanced concentration modulation Spectroscopy in the visible region. The (1, 2), (1, 3) and (2, 3) bands of c(3)Pi(u)-b(3)Pi(g) in the range 16620-17860 cm(-1) are observed and their (3)Pi(2)-(3)Pi(2) subbands are rotationally analysed. A set of effective molecular constants for the Omega = 2 component of the states involved are determined.
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页码:90 / 93
页数:4
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