Preparation of Activated Carbon from Sugarcane Bagasse Soot and Methylene Blue Adsorption

被引:38
|
作者
Giusto, Luana A. R. [1 ]
Pissetti, Fabio L. [1 ]
Castro, Talita S. [2 ]
Magalhaes, Fabiano [3 ]
机构
[1] Univ Fed Alfenas, Inst Quim, Rua Gabriel Monteiro da Silva,700, BR-37130000 Alfenas, MG, Brazil
[2] Univ Fed Minas Gerais, Dept Quim, Ave Pres Antonio Carlos,6627, BR-31270901 Belo Horizonte, MG, Brazil
[3] Univ Fed Lavras, Dept Quim, Caixa Postal 3037, BR-37200000 Lavras, MG, Brazil
来源
WATER AIR AND SOIL POLLUTION | 2017年 / 228卷 / 07期
关键词
Sugarcane bagasse soot; Physical activation; Activated carbon; Adsorption; Methylene blue; WASTE; SORPTION; KINETICS; BIOMASS; SLUDGE; ASH; ADSORBENTS; PRECURSORS; PYROLYSIS; ISOTHERM;
D O I
10.1007/s11270-017-3422-5
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Sugarcane bagasse soot is an agro-industrial residue rich in carbon that can be transformed into value-added materials, such as activated carbons. Therefore, this work aimed at producing activated carbon from sugarcane bagasse soot, using CO2 at 800, 850, and 900 C-omicron, and investigating its efficiency to adsorb methylene blue as model contaminant. The results showed that the surface area and pore volume increased in the obtained carbons, with high specific areas (up to 829 m(2)/g), and the isotherms of the N-2 adsorption describe mesoporous materials. The morphology of the prepared activated carbons showed that sugarcane bagasse soot and the activated carbons kept the fibrous structure of sugarcane bagasse, but after activation, they have cavities that resemble a honeycomb. Adsorption studies with methylene blue dye showed that the activation process resulted in adsorption capacities up to 11 times higher than sugarcane bagasse soot, which is comparable with commercial activated carbon. Dye adsorption kinetics could be described by a pseudo-second-order dependency in the studied materials, and the adsorption isotherms were better fitted by the Langmuir model. It is emphasized that cost-effective materials that are similar to commercial activated carbon were obtained.
引用
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页数:10
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