Effect of Polyethyleneoxide and Sodium Chloride Over the Micellization Behavior of Sodium Dodecyl Sulfate

被引：8
|
作者：
Baloch, Musa Kaleem [1 ]
Ahmad, Farzana [1 ]
Rauf, Abdur [1 ]
Durrani, Gulrez Fatima [1 ]
机构：
[1] Gomal Univ, Dept Chem, Dera Ismail Khan, Pakistan
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2009年 / 114卷 / 03期
关键词：
PEO; SDS; electrolytes; micellization; dynamic light scattering; surfactants; CHARGED POLYELECTROLYTE/SURFACTANT MIXTURES; AIR-WATER-INTERFACE; NEUTRON REFLECTION; AIR/WATER INTERFACE; POLY(STYRENE SULFONATE); POLY(ETHYLENE OXIDE); SALT-SOLUTIONS; ADSORPTION; SURFACTANT; POLYMER;
D O I：
10.1002/app.30321
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Micellization behavior of sodium dodecyl sulfate (SDS) and its mixture with polyethylene oxide (PEO) are investigated using surface tension and light scattering techniques. The data are presented and interpreted in a novel way, which provides more and reliable information about the interaction of the components. The concentration of SDS corresponding to the initiation of interaction with PEO (T(1)) and the saturation point (T(3)) are well identified in this way. It has been observed that the concentration span between T(1) and T(3) is not much affected by the amount of PEO added. The detail investigation of data concludes that SDS and PEO interactions are in one to one ratio at molecular level and CMC decreases with the addition of salt to the system and the micelles become more compact. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 114: 1444-1448, 2009
引用
收藏
页码：1444 / 1448
页数：5
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