Reactivity and hydrogen affinity of charged molybdenum oxoclusters in the gas phase

被引：0
|
作者：
Goncharov, V. B. [1 ]
机构：
[1] Russian Acad Sci, Boreskov Inst Catalysis, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2006年 / 80卷 / 03期
关键词：
D O I：
10.1134/S0036024406030320
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The available experimental data on proton affinity were used to calculate the hydrogen affinity (HA) of oxygen-containing molybdenum clusters. As the HA increases, the direct incorporation of the ion into a C-H bond of a hydrocarbon molecule gives way to the direct abstraction of the hydrogen atom accompanied by charge transfer to the organic fragment.
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收藏
页码：486 / 488
页数：3
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