Anion binding in metal-organic frameworks

被引：34

作者：

Wu, Xin ^{[1
]}

Macreadie, Lauren K. ^{[1
]}

Gale, Philip A. ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

COORDINATION CHEMISTRY REVIEWS | 2021年 / 432卷

基金：

澳大利亚研究理事会;

关键词：

Anion binding; Metal-organic framework; Anion adsorbent; Anion sensor; Supramolecular chemistry;

D O I：

10.1016/j.ccr.2020.213708

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Despite commonly being used as the hosts for gases, solvents and other neutral molecules, metal-organic frameworks (MOFs) have received recent attention as supramolecular anion binding hosts with a broad range of environmental and biological applications. The review summarizes the development of this area, with the anion-binding MOFs categorized based on different design strategies including cationic MOFs with anion-exchange capabilities, neutral MOFs that feature anion coordination to metal nodes, as well as MOFs functionalized with non-covalent or covalent anion-recognition motifs. We also discuss the advantages of using the MOF scaffold for anion binding compared with small-molecules anion receptors. (C) 2020 Elsevier B.V. All rights reserved.

引用

页数：18

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