Crystal and molecular structure of [(C6H5)(2)P(=O)(CH2CH2N(CH3)(3))(+)][I-]

被引：0

作者：

Churchill, MR ^{[1
]}

See, RF ^{[1
]}

Rominger, RL ^{[1
]}

Atwood, JD ^{[1
]}

机构：

[1] ST LOUIS UNIV,DEPT CHEM,ST LOUIS,MO 63103

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1996年 / 26卷 / 11期

关键词：

phosphine oxide; quaternary ammonium; water-soluble phosphine; crystal structure; hydrogen bonding;

D O I：

暂无

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound crystallizes in the centrosymmetric triclinic space group P (1) over bar with Z = 4. The crystallographic asymmetric unit contains two independent cations; interatomic distances within these include P=O = 1.47(1) and 1.47(1)Angstrom, P-C6H5 = 1.78(2)-1.81(1)Angstrom and P-CH(2)CH(2)NMe(3)(+) = 1.80(1) and 1.81(1)Angstrom. The phosphine oxide moiety is involved in intermolecular hydrogen bonding (O ... H-C, with O .. H greater than or equal to 2.42 Angstrom) and the iodide is involved in I ... H-C contacts with I ... H greater than or equal to 3.10 Angstrom.

引用

页码：747 / 752

页数：6

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