catena-Poly[[[2-(2-furyl)-1H-imidazo[4,5-f][1,10]phenanthroline]zinc(II)]-μ-benzene-1,2-dicarboxylato]

被引:1
|
作者
Li, Chuan-Bi
Li, Yan-Wei
Fang, Wei
Liu, Bo
Li, De-Qian [1 ]
机构
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Grad Sch, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
[2] Jilin Normal Univ, Dept Chem, Siping 136000, Peoples R China
关键词
D O I
10.1107/S1600536806049592
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Zn(C8H4O4)(C17H10N4O)](n), the Zn-II atom is five-coordinated by two N atoms from the phenanthro-line-derived ligand and three O atoms from one bidentate and one monodentate benzene-1,2-dicarboxylate (1,2-BDC) dianions in a distorted trigonal-bipyramidal geometry. The Zn-II atoms are bridged by the 1,2-BDC ligands to form a single-chain structure. Neighboring chains interact through pi-pi interactions, leading to a two-dimensional network.
引用
收藏
页码:M3541 / M3543
页数:3
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