Growth and investigation of new non-linear optical crystals of LAP family

被引：154
|
作者：
Petrosyan, AM
Sukiasyan, RP
Karapetyan, HA
Terzyan, SS
Feigelson, RS
机构：
[1] Stanford Univ, Ctr Mat Res, Stanford, CA 94305 USA
[2] NAS Armenia, MSRC, Yerevan 375014, Armenia
[3] Yerevan State Univ, Yerevan 375049, Armenia
来源：
JOURNAL OF CRYSTAL GROWTH | 2000年 / 213卷 / 1-2期
关键词：
non-linear optical crystals; LAP-analogs;
D O I：
10.1016/S0022-0248(00)00011-7
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The possibility of preparing new analogs of L-arginine phosphate monohydrate, (LAP), has been investigated. Single crystals of the compound L-Arg . HCOOH, which had earlier been obtained in powdered form, were successfully grown during the course of this investigation. In addition, we have found that there is a class of compounds having the Arg . 2Ax composition, (where Ax is one of several inorganic or organic acids). Such compounds (Arg . 2HIO(3), Arg . 2HNO(3), Arg . 2H(3)PO(4), Arg . 2HF, Arg . 2HCl . H2O, and Arg . 2HBr . H2O) have been synthesized and single crystals grown. The crystals grown in this investigation were studied by IR and X-ray diffraction methods. The influence of the different amino acid groups on crystal symmetry and the influence of this symmetry on non-linear optical properties are discussed. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：103 / 111
页数：9
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