Synthesis and Crystal Structure of Nickel(II) Cluster with Salen-Type Bisoxime Ligand

被引：0
|
作者：
Sun Yin-Xia [1 ]
Dong Wen-Kui [1 ]
Wang Li [1 ]
Zhao Li [1 ]
Yang Yu-Hua [1 ]
机构：
[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 25卷 / 08期
关键词：
nickel(II) cluster; salen-type bisoxime ligand; synthesis; crystal structure; INFRARED-SPECTRA; COMPLEXES;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A nickel(II) cluster, {[Ni(L)H2O](2)(OAc)(2)Ni}center dot 2EtOH, has been synthesized by the means of the complexation of nickel(II) acetate tetrahydrate with a new Salen-type bisoxime ligand (H2L, 4,4'-dimethoxy-2,2'-[ethylenedioxybis (nitrilo-methylidyne)]diphenol). The crystal structure shows that the hexacoodinated terminal nickel(II) ions lie in the N2O2 coordination sphere of Salen-type bisoxime ligands, quadruple mu-phenoxo oxygen atoms from two [NiL] chelates coordinated to the central nickel(II) ion, and the two acetate anions coordinated to three nickel(II) ions through Ni-O-C-O-Ni bridges. Thus, all the three nickel atoms of the cluster have distorted octahedral geometries. CCDC: 736762.
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页码：1478 / 1482
页数：5
相关论文
共 18 条
  • [1] Synthesis, characterization and equilibrium study of the dinuclear adducts formation between nickel(II) Salen-type complexes with diorganotin(IV) dichlorides in chloroform
    Asadi, Mozaffar
    Jamshid, Khosrow Aein
    Kyanfar, Ali Hossein
    [J]. INORGANICA CHIMICA ACTA, 2007, 360 (05) : 1725 - 1730
  • [2] A linear trinuclear CdII-CdII-CdII complex with a μ-acetato bridge:: bis{(μ-acetato)[μ-bis(salicylidene)-1,3-propanediaminato]-cadmium(II)}cadmium(II)
    Atakol, O
    Aksu, M
    Ercan, F
    Arici, C
    Tahir, MN
    Ülkü, D
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 1072 - 1075
  • [3] Tris(μ-phenoxo) bridged Cd(II) polymer synthesised from a symmetrical tripodal ligand:: A novel observation for heptadentate monocapped trigonal antiprismatic Schiff base complex
    Chakraborty, Joy
    Samanta, Brajagopal
    Pilet, Guillaume
    Mitra, Samiran
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (01) : 40 - 44
  • [4] Synthesis and crystal structure of a novel supramolecular nanotube copper(II) complex with 3,3′-dihydroxy-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol
    Dong, Wen-Kid
    Zhu, Chong-En
    Wu, Hui-Lu
    Ding, Yu-Jie
    Yu, Tian-Zhi
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2007, 37 (01) : 61 - 65
  • [5] Dong WK, 2008, CHINESE J INORG CHEM, V24, P1325
  • [6] Dong WK, 2008, CHINESE J INORG CHEM, V24, P10
  • [7] Synthesis, crystal structure, and properties of supramolecular CuII, ZnII, and CdII complexes with Salen-type bisoxime ligands
    Dong, Wen-Kui
    Sun, Yin-Xia
    Zhang, Yan-Ping
    Li, Li
    He, Xue-Ni
    Tang, Xiao-Lu
    [J]. INORGANICA CHIMICA ACTA, 2009, 362 (01) : 117 - 124
  • [8] Synthesis, crystal structure and infrared spectra of Cu(II) and Co(II) complexes with 4,4′-dichloro-2,2′-[ethylene dioxybis(nitrilomethylidyne)]diphenol
    Dong, Wenkui
    Shi, Junyan
    Xu, Li
    Zhong, Jinkui
    Duan, Jingui
    Zhang, Yanping
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2008, 22 (02) : 89 - 96
  • [9] Nickel(II) complexes with N2OS and N2S2 co-ordination spheres:: reduction and spectroscopic study of the corresponding Ni(I) complexes
    Gomes, L
    Pereira, E
    de Castro, B
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (08): : 1373 - 1379
  • [10] Kohawole G. A., 1981, J CHEM SOC DA, P1241
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