Palladium-catalyzed asymmetric alkoxycarbonylation of allyl phosphates

被引：19
|
作者：
Imada, Y [1 ]
Fujii, M [1 ]
Kubota, Y [1 ]
Murahashi, SI [1 ]
机构：
[1] OSAKA UNIV,GRAD SCH ENGN SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 47期
关键词：
D O I：
10.1016/S0040-4039(97)10201-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalyzed alkoxycarbonylation of allyl phosphates proceeds with high efficiency affording the corresponding beta,gamma-unsaturated esters stereoselectively with inversion of configuration at the allylic carbon center. Palladium complexes bearing chiral monodentate phosphine ligands are effective catalysts for asymmetric allylic carbonylation of cyclohex-2-en-1-yl phosphates 1 to give optically active cyclohex-2-ene-1-carboxylates 2 in moderate enantiomeric excesses. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：8227 / 8230
页数：4
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