Copper-mediated synthesis of α-trifluoromethylselenolated esters

被引：17
|
作者：
Chen, Taotao [1 ]
You, Yi [1 ]
Weng, Zhiqiang [1 ]
机构：
[1] Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environment, Fuzhou 350108, Fujian, Peoples R China
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2018年 / 216卷
基金：
中国国家自然科学基金;
关键词：
Trifluoromethylselenolation; Copper; alpha-Diazo esters; Fluorine; CATALYZED TRIFLUOROMETHYLSELENOLATION; NUCLEOPHILIC TRIFLUOROMETHYLATION; ELECTROPHILIC TRIFLUOROMETHYL; DIAZO ESTERS; DISULFIDES; ARYL; TRIMETHYLSILANE; SELENIDES; REAGENTS; HALIDES;
D O I：
10.1016/j.jfluchem.2018.10.002
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A copper-mediated synthesis of alpha-trifluoromethylselenolated esters was developed. Trifluoromethylselenolation of the aromatic and aliphatic alpha-diazo esters with [(bpy)Cu(SeCF3)](2) afforded alpha-trifluoromethylselenolated esters in good to excellent yields. Various important functional groups were tolerated in the ortho, meta, and para positions of the phenyl rings.
引用
收藏
页码：43 / 46
页数：4
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