Complete Conversion of Hydrous Hydrazine to Hydrogen at Room Temperature for Chemical Hydrogen Storage

被引：250
|
作者：
Singh, Sanjay Kumar [1 ]
Xu, Qiang [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Osaka 5638577, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 50期
关键词：
AMMONIA-BORANE; CATALYTIC DECOMPOSITION; GENERATION; NANOPARTICLES; OXIDATION; SURFACE; OXYGEN;
D O I：
10.1021/ja908037t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A synergic effect of Rh and Ni in the bimetallic Rh4Ni nanocatalyst (Rh/Ni ratio = 4:1) makes it possible to achieve a 100% selectivity for hydrogen generation by complete decomposition of hydrous hydrazine at room temperature. The Rh,Ni nanocatalysts with a particle size of similar to 3 nm were prepared by alloying Rh and Ni using a coreduction process in the presence of hexadecyltrimethyl ammonium bromide (CTAB).
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收藏
页码：18032 / +
页数：3
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