Dense PVDF-type polymer-in-ceramic electrolytes for solid state lithium batteries

被引:8
|
作者
Wu, Jiajie [1 ]
Wu, Xiaomeng [2 ]
Wang, Wenli [1 ]
Wang, Qian [1 ]
Zhou, Xiaoyu [1 ]
Liu, Yang [1 ,3 ]
Guo, Bingkun [1 ]
机构
[1] Shanghai Univ, Mat Genome Inst, Shanghai 200444, Peoples R China
[2] Shanghai Inst Space Power Sources, Space Power Technol State Key Lab, Shanghai 200245, Peoples R China
[3] Southern Univ Sci & Technol, Guangdong Prov Key Lab Energy Mat Elect Power, Shenzhen 518055, Peoples R China
关键词
NANOPARTICLES;
D O I
10.1039/d0ra03433a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Li7La3Zr1.4Ta0.6O12(LLZTO) and polyvinylidene fluoride (PVDF) composite electrolytes (LPCEs) with a high ceramic content up to 80 wt% have been developed. Hot pressing can significantly reduce the porosity of LPCEs and increase the conductivity to 1.08 x 10(-4)S cm(-1)at 60 degrees C, then the LPCEs can sustain Li plating/stripping cycling for over 1500 h, and make LiFePO4/LPCE/Li cell display a capacity retention of 86% in 200 cycles.
引用
收藏
页码:22417 / 22421
页数:5
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