Electrochemical Supercapacitors Based on Graphene-Conducting Polythiophenes Nanocomposite

被引:25
|
作者
Alvi, F. [1 ,2 ]
Ram, M. K. [4 ,5 ]
Basnayaka, P. [1 ]
Stefanakos, E. [2 ,5 ]
Goswami, Y. [3 ,5 ]
Hoff, A. M. [2 ]
Kumar, A. [1 ,4 ,5 ]
机构
[1] Univ S Florida, Dept Mech Engn, Tampa, FL 33620 USA
[2] Univ S Florida, Dept Elect Engn, Tampa, FL 33620 USA
[3] Univ S Florida, Dept Chem & Biomed Engn, Tampa, FL 33620 USA
[4] Univ S Florida, Nanotechnol Res & Educ Ctr, Tampa, FL 33620 USA
[5] Univ S Florida, Clean Energy Res Ctr, Tampa, FL 33620 USA
基金
美国国家科学基金会;
关键词
CAPACITANCE PROPERTIES; ELECTRODE; POLY(3,4-ETHYLENEDIOXYTHIOPHENE); COMPOSITES; POLYMER; PEDOT;
D O I
10.1149/1.3654215
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Supercapacitors represent an attractive alternative for portable electronics and automotive applications due to their high specific power, and extended lifetime. The poly (3, 4-ethylenedioxythiophene) (PEDOT) and polythiophene (PTh) have attracted much attention because of their excellent environmental stability, optical, electrical and electrochemical properties. We present here the synthesis, characterization and application of graphene (G)-PEDOT and G-PTh nanocomposites as electrode material for supercapacitor applications. These nanocomposites were synthesized using chemical oxidative polymerization technique, and characterized using Scanning Electron Microscopy (SEM), X-ray-diffraction, Electrochemical Impedance Spectroscopy (EIS), and Cyclic Voltammetry (CV) techniques. The electrochemical charge/discharge characteristics of G-PEDOT and G-PTh nanocomposites were investigated in 2M HCl electrolytic medium, and the specific discharge capacitance values were estimated to be varying from 160 to 400 Farad (F)/gram. This study has revealed that the G-PEDOT and G-PTh nanocomposite electrode materials may lead to a stable supercapacitor for portable electronic applications.
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页码:167 / 174
页数:8
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