The bonding of thiazoles to platinum(II) complexes. X-ray crystal structure of cis- and trans-[Pt(dimethyl sulfoxide)(thiazole)Cl-2]

被引：35
|
作者：
Cornia, A
Fabretti, AC
Bonivento, M
Cattalini, L
机构：
[1] UNIV VENICE,DIPARTIMENTO CHIM,I-30123 VENICE,ITALY
[2] UNIV MODENA,DIPARTIMENTO CHIM,I-41100 MODENA,ITALY
来源：
INORGANICA CHIMICA ACTA | 1997年 / 255卷 / 02期
关键词：
platinum complexes; thiazole complexes; dimethyl sulfoxide complexes; crystal structures;
D O I：
10.1016/S0020-1693(96)05391-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structures of neutral cis- and trans-[Pt(dimethyl sulfoxide) (thiazole)Cl-2] have been determined by X-ray diffraction. The longer C4-C5 bond distance of the N-coordinated thiazole in both the square planar complexes, as compared to the free ligand, is interpreted in terms of a negative charge density transfer toward the antibonding orbital system of the thiazolic ring.
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页码：405 / 409
页数：5
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