Solvent extraction of Os(IV) with 2-mercaptobenzothiazole into chloroform

被引:2
|
作者
Bahrainwala, TM [1 ]
Turel, ZR [1 ]
机构
[1] Inst Sci, Div Nucl Chem, Bombay 400032, Maharashtra, India
关键词
Physical Chemistry; Inorganic Chemistry; Chloroform; Solvent Extraction; Acidic Medium;
D O I
10.1007/BF02386687
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
2-mercaptobenzothiazole has been used for the solvent extraction of Os(IV) in acidic medium. The extraction of Os(IV) was found to be better than 90% over the pH range of 3.0 to 5.0 with an equilibration time of 5.0 minutes. The stoichiometry of metal:reagent determined by substoichiometric extraction and slope ratio method was found to be 1:4. Decontamination factor for various elements in the substoichiometric extraction of Os(IV) were also evaluated.
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页码:179 / 182
页数:4
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