Rhodium-catalysed substitutive arylation of cis-allylic diols with arylboroxines

被引：58
|
作者：
Miura, Tomoya [1 ]
Takahashi, Yusuke [1 ]
Murakami, Masahiro [1 ]
机构：
[1] Kyoto Univ, Dept Synth Chem & Biol Chem, Kyoto 6158510, Japan
来源：
CHEMICAL COMMUNICATIONS | 2007年 / 06期
关键词：
D O I：
10.1039/b612710j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Substitutive arylation of cis-allylic diols occurs upon treatment with arylboroxines in the presence of a rhodium(I) catalyst; the reaction proceeds through the addition of an intermediate arylrhodium(I) species across the carbon-carbon double bond and subsequent beta-oxygen elimination.
引用
收藏
页码：595 / 597
页数：3
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