Synthesis of Novel Spiro-Oxazino-Quinoline Derivatives and Study of Their Photophysical Properties

被引：18
|
作者：
Rane, Bhupendra S. [1 ]
Kazi, Muddassar A. [1 ]
Bagul, Sandeep M. [1 ]
Shelar, Deepak P. [1 ]
Toche, Raghunath B. [1 ]
Jachak, Madhukar N. [1 ]
机构：
[1] KTHM Coll, Dept Chem, Organ Chem Res Ctr, Nasik 422002, MS, India
来源：
JOURNAL OF FLUORESCENCE | 2010年 / 20卷 / 01期
关键词：
Spiro-oxazino-quinoline; Absorption and emission; Quantum yields; Heat of formation; HOMO-LUMO; OPTICAL-ABSORPTION; BEHAVIOR;
D O I：
10.1007/s10895-009-0557-9
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
A convenient route was successfully developed for the synthesis of novel heterocycles such as spiro-oxazino-quinoline derivatives from 2-aminoquinoline-3-carbonitrile (4) in good yield. The Spiro-quinoline derivatives (6, 8 and 10) were synthesized and further studied for their photophysical properties. Semiempirical molecular orbital calculation (PM3/PM6 for structure) proves to be a suitable tool for the prediction of absorption and fluorescence properties of these compounds.
引用
收藏
页码：415 / 420
页数：6
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