Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex

被引：122

作者：

Smith, JM ^{[1
]}

Lachicotte, RJ ^{[1
]}

Holland, PL ^{[1
]}

机构：

[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 17期

关键词：

D O I：

10.1039/b103635c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination number of the metal in iron(II) beta -diketiminate complexes can be tuned through the size of the alkyl substituents on the ligand backbone.

引用

页码：1542 / 1543

页数：2

共 38 条

[1] Ligand dependence of binding to three-coordinate iron(II) complexes
Chiang, Karen P.
Barrett, Pamela M.
Ding, Feizhi
Smith, Jeremy M.
Kingsley, Savariraj
Brennessel, William W.
Clark, Meghan M.
Lachicotte, Rene J.
Holland, Patrick L.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
[2] A three-coordinate iron-silylene complex stabilized by ligand-ligand dispersion forces
Hanninen, Mikko M.
Pal, Kuntal
Day, Benjamin M.
Pugh, Thomas
Layfield, Richard A.
DALTON TRANSACTIONS, 2016, 45 (28) : 11301 - 11305
[3] A cationic three-coordinate iron(II) complex and the reaction of β-diketiminate with ethyl diazoacetate
Gregory, EA
Lachicotte, RJ
Holland, PL
ORGANOMETALLICS, 2005, 24 (08) : 1803 - 1805
[4] Ligand Effects on Hydrogen Atom Transfer from Hydrocarbons to Three-Coordinate Iron Imides
Cowley, Ryan E.
Holland, Patrick L.
INORGANIC CHEMISTRY, 2012, 51 (15) : 8352 - 8361
[5] Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity
Liu, Yuesheng
Wang, Lei
Deng, Liang
ORGANOMETALLICS, 2015, 34 (17) : 4401 - 4407
[6] Convenient synthesis and crystal structure of a monomeric zinc hydride complex with a three-coordinate metal center
Spielmann, Jan
Piesik, Dirk
Wittkamp, Bernd
Jansen, Georg
Harder, Sjoerd
CHEMICAL COMMUNICATIONS, 2009, (23) : 3455 - 3456
[7] Synthesis and Reactivity of a Neutral, Three-Coordinate Platinum(II) Complex Featuring Terminal Amido Ligation
Kelly, Colin M.
Kwon, Doo-Hyun
Ferguson, Michael J.
Bischof, Steven M.
Sydora, Orson L.
Ess, Daniel H.
Stradiotto, Mark
Turculet, Laura
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (48) : 14498 - 14502
[8] Synthesis and structure characterization of three-coordinate silver(I) and seven-coordinate cobalt(II) coordination polymers with 4-pyridylthioacetate
Qin, SB
Ke, YX
Lu, SM
Li, JM
Pei, HX
Wu, XT
Du, WX
JOURNAL OF MOLECULAR STRUCTURE, 2004, 689 (1-2) : 75 - 80
[9] Synthesis of a sterically hindered three-coordinate Pd(II) complex for C-F reductive elimination
Kim, Sojung
Wang, Long
Chen, Liye
Carrow, Brad
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
[10] Mononuclear three-coordinate mercury(II)-thiolate complex: Synthesis and X-ray crystal structure
Kim, YY
Lee, HJ
Nam, HJ
Noh, DY
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2001, 22 (01): : 17 - 18

← 1 2 3 4 →