Recent Advances in Aryne Double Bond Insertion

被引：7
|
作者：
Wu, Chunrui [1 ]
Yang, Yupo [2 ]
Shi, Feng [1 ]
机构：
[1] Henan Univ, Key Lab Nat Med & lmmunoengn Henan Prov, Kaifeng 475004, Peoples R China
[2] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 35卷 / 04期
基金：
中国国家自然科学基金;
关键词：
aryne; ortho-quinomethide; reactive intermediate; pericyclic reaction; tandem reaction; COUPLING REACTION; STRAIGHTFORWARD SYNTHESIS; VINYLOGOUS AMIDES; O-QUINODIMETHANES; CARBON-CARBON; BENZYNE; CYCLOADDITIONS; BENZOFURANS; CHEMISTRY;
D O I：
10.6023/cjoc201411041
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aryne double bond insertion generates an ortho-quinomethide-typed intermediate, which, like aryne itself, is one of the most important reactive intermediates in organic reactions. This review summarizes recent advances in this field and the potential applications in synthetic organic chemistry, with a focus on the reaction mechanism, as well as the structure and reactivity of the ortho-quinomethide intermediates.
引用
收藏
页码：770 / 780
页数：11
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