Crystal structure and modeling calculation of the columnar helix 2,6-Bis(imino)phenoxy iron(III) chloride

被引：10

作者：

Han, LQ

Du, JL

Yang, HJ

Wang, HG

Leng, XB

Galstyan, A

Zaric, S

Sun, WH ^{[1
]}

机构：

[1] Chinese Acad Sci, State Key Lab Engn Plast, Beijing 100080, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China

[3] Nankai Univ, State Key Lab Funct Polymer, Tianjin 300071, Peoples R China

[4] Free Univ Berlin, Inst Chem, Dept Biol Chem & Pharm, D-14195 Berlin, Germany

[5] Univ Belgrade, Dept Chem, YU-11001 Belgrade, Serbia

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 01期

关键词：

self-assembly; ion pair; columnar helix; pi-pi interaction;

D O I：

10.1016/S1387-7003(02)00670-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystal structure of novel bis(imino)phenoxychloro-iron(III) chloride demonstrated a columnar helix through hydrogen bonding of anion-cation molecules and intermolecular pi-pi interactions, along with the syntheses and characterization of the new compounds. A quantum-chemical single point calculations of the interaction energies were performed on the basis of the X-ray structural data. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：5 / 9

页数：5

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