A water-stable triazine-based metal-organic framework as an efficient adsorbent of Pb(II) ions

被引:38
|
作者
Zhang, Ruoqian [1 ]
Liu, Yuanyuan [1 ]
An, Yang [1 ]
Wang, Zeyan [1 ]
Wang, Peng [1 ]
Zhen, Zhaoke [1 ]
Qin, Xiaoyan [1 ]
Zhang, Xiaoyang [1 ]
Dai, Ying [2 ]
Huang, Baibiao [1 ]
机构
[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Shandong, Peoples R China
[2] Shandong Univ, Sch Phys, Jinan 250100, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
Triazine-based metal-organic framework; Pb(II) adsorption; High adsorption capacity; Prior adsorption; Binding sites; ENHANCED REMOVAL; ADSORPTION; FUNCTIONALIZATION; BISMUTH; HG2+; STABILITY; MECHANISM; STRATEGY; SORPTION; CADMIUM;
D O I
10.1016/j.colsurfa.2018.10.011
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Effective and selective removal of Pb(II) from aqueous solution is highly desirable, but it is still a great challenge. We report here a water stable metal-organic frameworks (CAU-7-TATB), and the ligands contain N, which provides binding sites for metal ions. CAU-7-TATB exhibits fast adsorption kinetics, high adsorption capacity towards Pb(II). More importantly, CAU-7-TATB remains high prior adsorption towards Pb(II) in the presence of interfering ions like Cr(III), Co(II), Ni(II), Mn(II), Zn(II), Mg(II) and Ca(II), which is potentially applicable in removing Pb(II) from industrial water.
引用
收藏
页码:315 / 322
页数:8
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