Bioorganic chemistry of rigid-rod molecules:: Adventures with p-oligophenyis

被引：6

作者：

Baudry, Y ^{[1
]}

Baumeister, B ^{[1
]}

Das, G ^{[1
]}

Gerard, D ^{[1
]}

Matile, S ^{[1
]}

Sakai, N ^{[1
]}

Som, A ^{[1
]}

Sordé, N ^{[1
]}

Talukdar, P ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland

来源：

CHIMIA | 2002年 / 56卷 / 12期

关键词：

antibiotics; beta-barrels; enzyme mimics; ion channels; molecular recognition; sensors;

D O I：

10.2533/000942902777679948

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Studies on the usefulness of rigid-rod molecules to address pertinent questions of biological relevance are summarized. Emphasis is placed on (a) the supramolecular functional plasticity of rho-octiphenyl beta-barrels expressed in molecular recognition (adaptable synthetic hosts), molecular translocation (adaptable synthetic ion channels) and molecular transformation (esterases, RNases), (b) molecular recognition of polarized membranes by rigid push-pull rods, as well as (c) the synthetic organic chemistry of rigid-rod molecules.

引用

页码：667 / 671

页数：5

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