2-[(2-Carboxyphenyl)disulfanyl]benzoate(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)ammonium

被引:3
|
作者
Huo, Jian-Zhong [1 ]
机构
[1] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China
关键词
2,2'-DITHIODIBENZOIC ACID; COMPLEXES; ANTIPYRINE;
D O I
10.1107/S1600536809036952
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title molecular salt, C11H14N3O+center dot C14H9O4S2-, one of the carboxylic groups of the 2,2'-dithiodibenzoic acid is deprotonated and the exocyclic amino N atom of the 4-aminoantipyrine is protonated. In the anion, the dihedral angle between the two benzene rings is 73.51 (5)degrees and in the cation the dihedral angle between the phenyl ring and the five-membered ring is 65.79 (9)degrees. In the crystal structure, intermolecular N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds connect the anions and cations into chains along [010].
引用
收藏
页码:O2691 / U268
页数:14
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