A water-tolerant solid acid, Cs2.5H0.5PW12O40, for hydrolysis of esters in water

被引：22
|
作者：
Okuhara, T
Kimura, M
Nakato, T
机构：
来源：
APPLIED CATALYSIS A-GENERAL | 1997年 / 155卷 / 01期
关键词：
heteropoly compound; water-tolerant solid acid; acidic Cs salt; zeolites; hydrolysis of ester;
D O I：
10.1016/S0926-860X(97)00062-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrolysis of esters in large excess water catalyzed by various solid and liquid acids has been studied. It was found that a solid CS(2.5)H(0.5)PW(12)O(4)0 was remarkably active for the hydrolysis of 2-methylphenylacetate in excess water, while other inorganic solid acids like H-ZSM-5, Nb2O5, or SO42-/ZrO2, were almost inactive. In addition, only the solution after the removal of the solid did not show any activity, and the activity of Cs2.5H0.5PW12O40 remained almost unchanged after it was treated in water (353 K) for 72 h.
引用
收藏
页码：L9 / L13
页数：5
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