Easily Recycled CuMgFe Catalysts Derived from Layered Double Hydroxides for Hydrogenolysis of Glycerol

A series of CuMgFe catalysts with different (Cu + Mg)/Fe molar ratios derived from hydrotalcites were prepared by coprecipitation for the hydrogenolysis of glycerol to 1,2-propanediol (1,2-PDO). X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectra (XPS), vibrating sample magnetometer (VSM), hydrogen temperature-programmed reduction (H-2 -TPR), CO2-TPD, and H-2-TPD (temperature-programmed desorption of CO2 and H-2) were used to investigate the physicochemical properties of the catalysts. The CuMgFe-layered double oxides (CuMgFe-4LDO) catalyst with (Cu + Mg)/Fe molar ratio of 4 exhibited superior activity and stability. The high glycerol conversion and 1,2-propanediol selectivity over CuMgFe-4LDO catalyst were attributed to its strong basicity, excellent H-2 activation ability, and an increase in the surface Cu content. The CuMgFe catalysts could be easily recycled with the assistance of an external magnetic field due to their magnetism.