Study on wet-laid nonwoven separator of lithium-ion battery

被引:8
|
作者
Wang Yi [1 ]
Dou Xiaoli [1 ]
Yao Yunzhen [1 ]
Liang Yun [1 ]
Hu Jian [1 ]
Zhan Huaiyu [1 ]
机构
[1] S China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510641, Guangdong, Peoples R China
关键词
Separator; nonwoven; para-phenylene terephthalamide; fibrillation;
D O I
10.1177/0040517511431314
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
In this paper, a new kind of wet-laid nonwoven material composed of highly fibrillated PPTA (para-phenylene terephthalamide) pulp is used in the preparation of a lithium-ion battery separator. Because the PPTA pulp is composed of fibrils and micro-fibrils, which are mostly less than 1 mu m in diameter, the pore size of the separator could be well controlled to less than 1 mu m. The effects of PPTA pulp on the pore structure of the separator, thermo-stability, electrochemical property and mechanical properties are researched. The results show that with the increase of PPTA pulp dosage, the pore size of separator is decreased. In addition, this type of separator shows excellent thermal stability. The strength retention of the nonwoven separator is 45% after it is stored at 180 degrees C for 10 minutes, but the polyolefin membrane is completely molten under the same conditions.
引用
收藏
页码:1659 / 1665
页数:7
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