Cellulose supramolecular structure changes during activation by organophosphorus compounds

被引:1
|
作者
Sidikov, AS [1 ]
Rakhmanberdiev, GR [1 ]
机构
[1] Tashkent Chem Engn Inst, Tashkent, Uzbekistan
关键词
cotton cellulose; activation; supramolecular structure;
D O I
10.1023/A:1017584313401
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
Cellulose supramolecular structure changes during activation by organophosphorus compounds were studied by electron microscopy, IR spectroscopy, and x-ray diffraction. These processes were shown to enhance interfibrillar swelling, weakening the intermolecular H-bonds between cellulose microfibrils, and loosening of the packing. As a result, the accessibility of esterification reagents to the molecules is improved.
引用
收藏
页码:620 / 622
页数:3
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