Conformational analysis of enantiomers of chiral chloroalkanes

被引:0
|
作者
Gunasekaran, S [1 ]
Ponnambalam, U [1 ]
Sathyanarayanamoorthi, V [1 ]
机构
[1] Pachaiyappas Coll, Post Grad & Res Dept Phys, Madras 600030, Tamil Nadu, India
关键词
conformational analysis; enantiomers; 2-chloropentane; 2-chlorohexane; 2-chloroheptane;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The pairs of compounds that are nonsuperimposable mirror images called enantiomers. There are several classes of enantiomers that are being studied rather extensively because of their industrial and research importance. 2-Chloropentane, 2-chlorohexane and 2-chloroheptane are the most important chiral enantiomers. Conformational analysis is the study of the energies of different conformations. Many reactions depend on a molecule's ability to twist into a particular conformation. Conformational analysis can help to predict which conformations are favoured and which reactions are more likely to take place. Here we apply conformational analysis to these three enantiomers. From these we predict the most stable conformer. Besides that, the successful interpretations of these compounds using various parameters of the molecules have been provided.
引用
收藏
页码:239 / 244
页数:6
相关论文
共 50 条
  • [1] Molecular conformational transition of chiral conjugated enantiomers dominated by Wallach's rule
    Yu, Meng-Na
    Li, Yin-Xiang
    Xu, Man
    Lin, Jin-Yi
    Gu, Jia-Bin
    Sun, Ning-
    Lin, Dong-Qing
    Wang, Yong-Xia
    Xie, Ling-Hai
    Huang, Wei
    JOURNAL OF MATERIALS CHEMISTRY C, 2021, 9 (22) : 6991 - 6995
  • [2] Preparation, conformational analysis and behaviour as chiral solvating agents of 9-anthrylpentafluorophenylmethanol enantiomers:: study of the diastereomeric association
    Pérez-Trujillo, M
    Virgili, A
    Molins, E
    TETRAHEDRON-ASYMMETRY, 2004, 15 (10) : 1615 - 1621
  • [3] Chiral Solid Solutions for the NMR Analysis of Enantiomers: A Potential New Approach to Chiral Analysis
    Klika, Karel D.
    JOURNAL OF SPECTROSCOPY, 2013, 2013
  • [4] Quantum mechanical study of additivity of conformational energy in chloroalkanes
    Satkovskiene, Dalia
    Jankauskas, Rytis
    Pipiraite, Prane
    Sulskus, Juozas
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 2007, 816 (1-3): : 43 - 51
  • [5] Trace analysis in chiral separation of selected amino enantiomers
    Pronce, T
    Tilquin, B
    JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 1996, 14 (8-10) : 1175 - 1184
  • [6] Enantiomers of Single Chirality Nanotube as Chiral Recognition Interface for Enhanced Electrochemical Chiral Analysis
    Pu, Chunling
    Xu, Yunxia
    Liu, Qi
    Zhu, Anwei
    Shi, Guoyue
    ANALYTICAL CHEMISTRY, 2019, 91 (04) : 3015 - 3020
  • [7] Chiral recognition of propranolol enantiomers by chiral ionic liquid: A quantum chemical calculation analysis
    Sedghamiz, Tahereh
    Ghalami, Farhad
    Sedghamiz, Elaheh
    Bahrami, Maryam
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2018, 1140 : 38 - 48
  • [8] CONFORMATIONAL-ANALYSIS OF CHIRAL HINDERED AMIDES
    RAUK, A
    TAVARES, DF
    KHAN, MA
    BORKENT, AJ
    OLSON, JF
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1983, 61 (11): : 2572 - 2580
  • [9] Conformational analysis of chiral ferrocene-peptides
    Heinze, K
    Beckmann, M
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (17) : 3450 - 3457
  • [10] CONFORMATIONAL-ANALYSIS OF CHIRAL POLYMERS IN SOLUTION
    CIARDELLI, F
    SALVADORI, P
    PURE AND APPLIED CHEMISTRY, 1985, 57 (07) : 931 - 940