Biodegradable Holographic Polymer-Dispersed Liquid Crystal

被引:0
|
作者
Sun, K. R. [1 ]
Jang, M. W. [1 ]
Park, H. C. [2 ]
Jeong, H. M. [3 ]
Yoon, K. S. [3 ]
Kim, B. K. [1 ]
机构
[1] Pusan Natl Univ, Dept Polymer Sci & Engn, Pusan 609735, South Korea
[2] Pusan Natl Univ, Sch Mat Sci & Engn, Pusan 609735, South Korea
[3] Univ Ulsan, Dept Chem, Ulsan 680749, South Korea
来源
关键词
biodegradable; electro-optical properties; glucose; HPDLC; modification; MONOMER FUNCTIONALITY; TRANSMISSION GRATINGS; FILMS; MATRIX; PERFORMANCE; COMPOSITES; MORPHOLOGY;
D O I
10.1080/00222341003785177
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The a-D-glucose was chemically modified with an allyl isocyanate (MG) and introduced into the polymer matrix for holographic polymer-dispersed liquid crystal (HPDLC), and the effects were studied in terms of morphology, grating formulation dynamics and electro-optical and biodegradable properties. Phase separation and diffraction efficiency increased at low content of (MG 4 wt%), while a rapid increase in crosslink density entrapped the LC droplets within the polymer to give poor phase separation, small droplet size, and low diffraction efficiency at high content. The HPDLC film was driven only with the addition of MG due to the increased droplet size with a minimum driving voltage of 18 V at 6.0 wt% MG. With the addition and an increasing amount of MG, the biodegradation of the composite film in a buffer solution was significantly increased in proportion to its amount.
引用
收藏
页码:795 / 805
页数:11
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